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Liquid chromatography-mass spectrometry (revision 1)

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Liquid chromatography-mass spectrometry
AbbreviationLC-MS
CombinesChromatographic separation and mass detection
InterfaceUsually electrospray
AddsIdentity to a retention-based separation
Analytical method infobox · conventions

Liquid chromatography-mass spectrometry couples a chromatographic separation to a mass spectrometer, so that each eluting peak is characterised by both its retention time and its mass. It converts a weak identification into a strong one.[1]

The interface is almost always electrospray, which works directly from flowing solution. This compatibility is what made the technique routine, and it constrains the chromatography: mobile phases must be volatile and free of non-volatile buffers.[2]

References

  1. ^ Aebersold R, Mann M. "Mass spectrometry-based proteomics." Nature 422(6928):198–207 (2003). PMID 12634793.
  2. ^ Fenn JB, Mann M, Meng CK, Wong SF, Whitehouse CM. "Electrospray ionization for mass spectrometry of large biomolecules." Science 246(4926):64–71 (1989). PMID 2675315.