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Temperature excursion: difference between revisions

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62The corresponding position for lyophilised research peptides is that no such allowance exists in a documented form. Supplier storage statements are recommendations, and the periods sometimes quoted for ambient tolerance are not supported by an identifiable stability study. The physical argument for the robustness of a dry cake is set out at [[Lyophilisation]] and is a reason to expect tolerance, not a substitute for having measured it.{{r|ppexcursion}}62The corresponding position for lyophilised research peptides is that no such allowance exists in a documented form. Supplier storage statements are recommendations, and the periods sometimes quoted for ambient tolerance are not supported by an identifiable stability study. The physical argument for the robustness of a dry cake is set out at [[Lyophilisation]] and is a reason to expect tolerance, not a substitute for having measured it.{{r|ppexcursion}}
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+64{{seealso|Cold chain|Peptide stability table}}
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64== Quantifying an excursion ==66== Quantifying an excursion ==
65Where an excursion consists of warming, its cumulative effect is summarised by the mean kinetic temperature. For intervals of duration ''t''<sub>i</sub> at absolute temperatures ''T''<sub>i</sub>:67Where an excursion consists of warming, its cumulative effect is summarised by the mean kinetic temperature. For intervals of duration ''t''<sub>i</sub> at absolute temperatures ''T''<sub>i</sub>:
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75{{math|(96 × 22 + 624 × 5) ÷ 720 = (2112 + 3120) ÷ 720 = 7.27 °C}}77{{math|(96 × 22 + 624 × 5) ÷ 720 = (2112 + 3120) ÷ 720 = 7.27 °C}}
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+79which lies inside the labelled range. The mean kinetic temperature, however, weights by degradation. With T = 295.15 K and 278.15 K:
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77== References ==81== References ==