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Peptide synthesis: difference between revisions

Diff·revision 15 → 16·23:29, 15 Jan 2025

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Revision 15 — 06:21, 27 Dec 2024
CostPerMgCory (talk)
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Revision 16 — 23:29, 15 Jan 2025
ArchiveBot (talk)
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28The material lost is not simply absent — it is present as truncated and deletion sequences, which remain attached to the support and are cleaved along with the target. These are the impurities that dominate a [[Crude peptide|crude]] peptide and that a purity method must resolve.28The material lost is not simply absent — it is present as truncated and deletion sequences, which remain attached to the support and are cleaved along with the target. These are the impurities that dominate a [[Crude peptide|crude]] peptide and that a purity method must resolve.
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+30Difficult sequences make the arithmetic worse. Aggregation of the growing chain on the support hides the reactive terminus and depresses coupling yields locally, which is why particular regions of a sequence rather than the whole are usually responsible for a poor crude. See [[Solid-phase peptide synthesis]].{{r|merrifield1963}}
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30== References ==32== References ==
31{{reflist}}33{{reflist}}